Aluminum chloride is a chemical compound with the chemical formula AlCl3. When contaminated with iron chloride, it often displays a yellow color compared to the white pure compound. It is used in various chemical applications as a Lewis base, with anhydrous aluminium trichloride being the most commonly used Lewis acid.
In its solid state, AlCl3 features a cubic close-packed layered structure and has an octahedral coordination geometry. As a liquid or in a molten state, it exists as a dimer with a tetrahedral coordination geometry. At higher temperatures, the dimers dissociate into a trigonal planar structure.
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